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To achieve this precision, geochronologists have had to develop the ability to isolate certain high-quality minerals that can be shown to have remained closed to migration of the radioactive parent atoms they contain and the daughter atoms formed by radioactive decay over billions of years of geologic time.
In addition, they have had to develop special techniques with which to dissolve these highly refractory minerals without contaminating the small amount about one-billionth of a gram of contained lead and uranium on which the age must be calculated.
Since parent uranium atoms change into daughter atoms with time at a known rate, their relative abundance leads directly to the absolute age of the host mineral. In fact, even in younger rocks, absolute dating is the only way that the fossil record can be calibrated.